Doubly N-confused pentaphyrins.
Doubly N-confused pentaphyrins.
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DOI：
10.1002/anie.200453732
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发表时间：
2004-05
影响因子：
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通讯作者：
A. Srinivasan;Tomoya Ishizuka;H. Maeda;H. Furuta
中科院分区：
文献类型：
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作者：
A. Srinivasan;Tomoya Ishizuka;H. Maeda;H. Furuta
混乱的三吡喃和混乱的二吡咯甲烷二甲醇的[3+ 2]偶联，然后氧化，导致合成mesopentafluorophenyl-substituted，doubly N-confused，oxo-substituted pentaphyrins（参见X射线晶体结构;绿色：F，蓝色：N，红色：O）。氧代吡咯部分已被证明容易形成分子内和分子间氢键。
Adding to the confusion:[3+ 2] coupling of confused tripyrrane and confused dipyrromethane dicarbinol, followed by oxidation, results in the synthesis of mesopentafluorophenyl-substituted, doubly N-confused, oxo-substituted pentaphyrins (see X-ray crystal structure; green: F, blue: N, red: O). The oxopyrrole moieties have been shown to readily form intra-and intermolecular hydrogen bonds.