Well-defined hydrogen and organofunctional polysiloxanes with spiro-fused siloxane backbones

Well-defined hydrogen and organofunctional polysiloxanes with spiro-fused siloxane backbones
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DOI：
10.1039/d0py01503b
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发表时间：
2021
期刊：
Polymer Chemistry
影响因子：
4.6
通讯作者：
Takahiro Kawatsu;Keita Fuchise;K. Takeuchi;Jun‐Chul Choi;Kazuhiko Sato;Kazuhiro Matsumoto
Takahiro Kawatsu;Keita Fuchise;K. Takeuchi;Jun‐Chul Choi;Kazuhiko Sato;Kazuhiro Matsumoto
中科院分区：
化学2区
文献类型：
--
作者：
Takahiro Kawatsu;Keita Fuchise;K. Takeuchi;Jun‐Chul Choi;Kazuhiko Sato;Kazuhiro Matsumoto

文献摘要

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采用B(C6F5)3催化脱氢交偶联法合成了结构明确、具有独特螺硅氧烷单元和有序排列的Si-H基团的大环聚硅氧烷。
Structurally well-defined macrocyclic polysiloxanes with unique spirosiloxane units and regularly arranged Si–H groups were synthesized by B(C6F5)3-catalyzed dehydrocarbonative cross-couplings.