Heterometallic Tetrazole Coordination Polymer Formed through 2 + 3 Cycloaddition Reaction between Inorganic Complexes in the Presence of Lewis Acid
Heterometallic Tetrazole Coordination Polymer Formed through 2 + 3 Cycloaddition Reaction between Inorganic Complexes in the Presence of Lewis Acid
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DOI：
10.1021/cg070528g
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发表时间：
2007-11
影响因子：
3.8
通讯作者：
Yunzhi Tang;Guo-xi Wang;Qiong Ye;R. Xiong;R. Yuan
中科院分区：
文献类型：
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作者：
Yunzhi Tang;Guo-xi Wang;Qiong Ye;R. Xiong;R. Yuan
在路易斯酸CuCl2和氯化镉存在下，在路易斯酸CuCl2和氯化镉存在下，双(3-氰基吡啶)铜(II)叠氮铜(A)的两个原位2+3分子间环加成反应分别提供了(3-C5H4N-CN4)2Cu(I)2(1)和(3-C5H4N-CN4)Cu(I)Cd(II)Cl2(2)的三维新型四唑配位聚合物，其中A取代了ʼS四唑合成中的有机氰基和NaN3。报道了它们有趣的发光性质。
The two in situ 2 + 3 intermolecular cycloaddition reactions between inorganic complexes bis(3-cyanopyrdine)copper(II)azide (A) offer homometallic and heterometallic 3D novel tetrazole coordination polymers, (3-C5H4N-CN4)2Cu(I)2 (1) and (3-C5H4N-CN4)Cu(I)Cd(II)Cl2 (2), respectively, in the presence of Lewis acid CuCl2 and CdCl2 in which A is used to replace the organic cyano group and NaN3 during Sharplessʼs tetrazole synthesis. Their interesting luminescent properties are reported.