"A Heterospin Pressure Sensor"
"A Heterospin Pressure Sensor"
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“异旋压力传感器”
DOI：
10.1039/c5tc01005e
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
V. I. Ovcharenko,
中科院分区：
文献类型：
--
作者：
K. Y. Maryunina,a X. Zhang;S. Nishihara;K. Inoue;V. A. Morozov;G. V. Romanenko;V. I. Ovcharenko,
首次研究了外压对Cu（II）氮氧配合物[Cu（hfac）2NN-PzMe]异自旋晶体磁性的影响。静水压力增加到0.14 GPa引起的磁异常温度的显着转变（从150 K到300 K）。这种复合物实际上起着高度敏感的外部压力传感器的作用。
The effect of external pressure on the magnetic properties was studied for the first time for heterospin crystals based on the Cu(II) complex with nitroxide [Cu(hfac)2NN-PzMe], which exhibits a spin-crossover-like phenomenon. An increase in the hydrostatic pressure to 0.14 GPa caused a significant shift of the magnetic anomaly temperature (from 150 K to 300 K). This complex actually functions as a highly sensitive external pressure sensor.