Synthesis and applications of core-enlarged perylene dyes
Synthesis and applications of core-enlarged perylene dyes
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DOI：
10.1039/c000137f
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发表时间：
2010-01-01
影响因子：
--
通讯作者：
Muellen, Klaus
中科院分区：
文献类型：
--
作者：
Avlasevich, Yuri;Li, Chen;Muellen, Klaus
二萘嵌苯染料不仅具有高的化学和光化学稳定性、高摩尔吸光系数和荧光量子产率，而且通过引入疏水或亲水取代基、电子供体或受体以及用于连接到聚合物或生物分子的官能团而提供广泛的化学官能化可能性。在过去的十年中，新的同系物（含有额外的萘单元和轴承额外的芳香环）的苝已被报道。本文综述了大核染料的合成路线及其应用。
Perylene dyes not only feature high chemical and photochemical stability, high molar absorptivities and fluorescence quantum yields but also offer wide possibilities for chemical functionalisation via the introduction of hydrophobic or hydrophilic substituents, electron donors or acceptors, and functional groups for attachment to polymers or biomolecules. In the past decade, novel homologues of perylene (containing additional naphthalene units and bearing additional aromatic rings) have been reported. In this article, we summarise synthetic routes to core-enlarged perylene dyes as well as their practical applications.