Surface-Enhanced Raman Scattering

Surface-Enhanced Raman Scattering
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DOI:
10.1007/978-1-4613-0985-7_6
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发表时间:
1988
期刊:
--
影响因子:
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通讯作者:
R. Birke;J. Lombardi
R. Birke;J. Lombardi
中科院分区:
其他
文献类型:
--
作者:
R. Birke;J. Lombardi

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表面增强拉曼散射(SERS)已经在固/溶液、固/气、固/真空、固/固界面上被观测到,它可能是作为分析探针的最灵敏的表面高分辨率振动光谱技术。自1977年以来,物理、化学和材料科学研究界关于这项技术的出版物数量激增,证明了人们对SERS的极大兴趣。对SERS感兴趣的一个原因是该技术关于与固体表面接触的材料相的性质的一般性。另一个原因是,有几个机制促成了SERS,在确定各种机制对全面加强的贡献程度方面存在着相当大的科学挑战。
Surface-enhanced Raman scattering (SERS) has been observed at solid/solution, solid/gas, solid/vacuum, and solid/solid interfaces, and it is possibly the most sensitive surface high-resolution vibrational spectrosopic technique available as an analytical probe. The great interest in SERS is evidenced by the virtual explosion in the number of publications dealing with this technique since 1977 from the physics, chemistry, and materials science research communities. One reason for this interest in SERS is the generality of the technique with regard to the nature of the material phase in contact with the solid surface. Another reason is that there are several mechanisms that contribute to SERS, and a considerable scientific challenge exists in determining the extent of the contributions of various mechanisms to the overall enhancement.