Magnetic/conducting bifunctionality due to π/σ-conjugated functional moieties in a stacked ferrimagnetic chain.

Magnetic/conducting bifunctionality due to π/σ-conjugated functional moieties in a stacked ferrimagnetic chain.
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DOI：
10.1021/ic101564x
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发表时间：
2010-09
期刊：
Inorganic chemistry
影响因子：
4.6
通讯作者：
H. Miyasaka;Y. Asai;Natsuko Motokawa;K. Kubo;M. Yamashita
H. Miyasaka;Y. Asai;Natsuko Motokawa;K. Kubo;M. Yamashita
中科院分区：
化学2区
文献类型：
--
作者：
H. Miyasaka;Y. Asai;Natsuko Motokawa;K. Kubo;M. Yamashita

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在8.6 K下，由[Ru（2）（II，III）（O（2）CEt）（4）]（+）（EtCO（2）（-）=丙酸根）和[Pt（mnt）（2）]（-）（mnt（2-）=马来腈二硫纶）组成的桨轮交替链分别具有S = 3/2和1/2局域自旋的亚铁磁自旋排列，以及具有倾斜模式的三维反铁磁有序.该链在[Pt（mnt）（2）]（-）单元处堆叠，以在垂直于链的方向上形成滑动柱，其充当导电的通路。
An alternating chain of a paddlewheel [Ru(2)(II,III)(O(2)CEt)(4)](+) (EtCO(2)(-) = propionate) complex and [Pt(mnt)(2)](-) (mnt(2-) = maleonitriledithiolate) has a ferrimagnetic spin arrangement of S = 3/2 and 1/2 local spins, respectively, as well as three-dimensional antiferromagnetic ordering with a canting mode at 8.6 K. This chain is stacked at the [Pt(mnt)(2)](-) units to form a slipped column in the vertical direction against the chain, which acts as a pathway for electrical conduction.