An anti-galvanic replacement reaction of DNA templated silver nanoclusters monitored by the light-scattering technique.
An anti-galvanic replacement reaction of DNA templated silver nanoclusters monitored by the light-scattering technique.
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DOI：
10.1039/c3cc44126a
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发表时间：
2013-08
影响因子：
4.9
通讯作者：
Guoliang Liu;Da-Qian Feng;Wen-jie Zheng;Tianfeng Chen;Dan Li
中科院分区：
文献类型：
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作者：
Guoliang Liu;Da-Qian Feng;Wen-jie Zheng;Tianfeng Chen;Dan Li
观察到了以单链DNA为模板的超小银纳米团簇还原铜(II)离子形成银铜合金纳米颗粒的反电偶置换反应(AGRR)。该反应违反了经典的原电池理论，并通过光散射技术进行了灵敏的监测。
An anti-galvanic replacement reaction (AGRR) of copper(II) ions reduced by ultra-small ssDNA-templated silver nanoclusters forming Ag-Cu alloy nanoparticles was observed. The reaction is against the classic galvanic theory and was monitored sensitively by the light-scattering technique.