Anion-directed assembly of a rectangular supramolecular cage in the solid state with electron-deficient phenoxylated oxacalix[2]arene[2]triazine.
Anion-directed assembly of a rectangular supramolecular cage in the solid state with electron-deficient phenoxylated oxacalix[2]arene[2]triazine.
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DOI：
10.1039/c2cc36465d
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发表时间：
2012-10
影响因子：
4.9
通讯作者：
De‐Xian Wang;Shixin Fa;Yang Liu;Bao-Yong Hou;Mei-Xiang Wang
中科院分区：
文献类型：
--
作者：
De‐Xian Wang;Shixin Fa;Yang Liu;Bao-Yong Hou;Mei-Xiang Wang
氯离子-π相互作用以及孤对电子-π相互作用、氢键和π-π堆积诱导了母体大环在固体状态下的六聚体组装成一个矩形超分子笼。
Chloride-π interaction along with lone-pair electrons-π interaction, hydrogen bonding and π-π stacking induced the hexameric assembly of the parent macrocycle into a rectangular supramolecular cage in the solid state.