Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates
Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates
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DOI：
10.1039/c4ob01739k
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发表时间：
2014-11-14
影响因子：
3.2
通讯作者：
Wu, Yangjie
中科院分区：
文献类型：
--
作者：
Mi, Xia;Wang, Chenyang;Wu, Yangjie
Silver-catalyzed carbonphosphonation of alpha,alpha-diaryl allylic alcohols is achieved. A series of gamma-ketophosphonates with different substituents were readily obtained. The mechanistic study indicated that the reaction was initiated by the addition of P-radicals, which sequentially undergo 1,2-migration of an aryl group to form C(Ar)-C(sp(3)) bonds.
