Single-crystal-to-single-crystal transformation from 1 D staggered-sculls chains to 3 D NbO-type metal-organic framework through [2+2] photodimerization.
Single-crystal-to-single-crystal transformation from 1 D staggered-sculls chains to 3 D NbO-type metal-organic framework through [2+2] photodimerization.
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DOI：
10.1002/chem.201200226
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发表时间：
2012-06
期刊：
影响因子：
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通讯作者：
Yong-Cong Ou;Da-Shuai Zhi;Wen-Ting Liu;Z. Ni;M. Tong
中科院分区：
文献类型：
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作者：
Yong-Cong Ou;Da-Shuai Zhi;Wen-Ting Liu;Z. Ni;M. Tong
通过[2+2]光二聚反应合成三维结构的新方法，将一维交错双桨链[M（1，2-chdc）（bpe）（2）（H（2）O）（2）]<$H（2）O（M = Zn，Mn）的两种异构体通过紫外光照射以单晶到单晶的方式转化为三维NbO型金属有机骨架. (see图; bpe =反式-1，2-（双（4-吡啶基）乙烯，chdc =环己烷二羧酸酯）。
A new approach to synthesize 3D structures through a [2+2] photodimerization process has been carried out by transforming two isostructures of 1D staggered-sculls chains [M(1,2-chdc)(bpe)(2)(H(2)O)(2)]⋅H(2)O (M = Zn, Mn) into 3D NbO-type metal-organic frameworks through UV irradiation in single-crystal-to-single-crystal mode. (see figure; bpe = trans-1,2-(bis(4-pyridyl)ethene, chdc =cyclohexanedicarboxylate).