Metal‐Catalyzed Hydrophosphination
Metal‐Catalyzed Hydrophosphination
复制标题
金属催化氢磷化
DOI：
10.1002/cctc.202200988
复制
发表时间：
2022
期刊：
影响因子：
4.5
通讯作者：
Waterman, Rory
中科院分区：
文献类型：
--
作者：
Novas, Bryan T.;Waterman, Rory
从农业到精细化学品，有机膦已经引起了许多领域的关注。磷资源的一次性利用使得磷的可持续利用成为总体上的当务之急。氢磷化是选择性地制备P-−-C键的有效方法，提供了一系列含磷分子，同时最大限度地提高了磷的有效利用。自从1958年第一份报告以来，已经出现了一系列用于氢磷化的催化剂，在某些情况下，这是一种自发的反应。这篇综述介绍了到2022年年中基于已知催化剂的文献的代表性观点，强调了对独特底物的扩展和选择性方面的进展。虽然已经出现了几篇关于这种转化方面的优秀评论，但这篇评论是对已报道的催化剂的全面指导。
Organophosphines have garnered attention from many avenues ranging from agriculture to fine chemicals. One‐time use of phosphate resources has made sustainable use of phosphorus overall imperative. Hydrophosphination serves as an efficient method to selectively prepare P−C bonds, furnishing a range of phosphorus‐containing molecules while maximizing the efficient use of phosphorus. Since the first report in 1958, a wide array of catalysts have appeared for hydrophosphination, a reaction that is spontaneous in some instances. This review presents a representative view of the literature based on known catalysts through mid‐2022, highlighting extensions to unique substrates and advances in selectivity. While several excellent reviews have appeared for aspects of this transformation, this review is meant as a comprehensive guide to reported catalysts.