Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex
Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex
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DOI：
10.1039/b611784h
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发表时间：
2006-01-01
影响因子：
4.9
通讯作者：
Wang, Jun
中科院分区：
文献类型：
--
作者：
Davies, Noel W.;Frey, Alistair S. P.;Wang, Jun
大环有机钐（II）络合物已被证明提供了二氧化碳的还原性反硝化的第一个实例，在环境条件下在容易的反应中得到碳酸盐络合物和一氧化碳。
A macrocyclic organosamarium(II) complex has been shown to provide the first example of the reductive disproportionation of carbon dioxide, giving a bimetallic carbonate complex and carbon monoxide in a facile reaction under ambient conditions.