Total synthesis of (+)-amphidinolide P. [corrected].
Total synthesis of (+)-amphidinolide P. [corrected].
复制标题
( )-amphidinolide P 的全合成。[已更正]。
作者：
David R. Williams;B. Myers;L. Mi
报道了收敛对映控制的15元内酯(-)-两萜内酯P的全合成。关键转化包括Sakurai烯丙化，stile偶联形成完全功能化的无环前体，以及分子内酯交换。
The convergent enantiocontrolled total synthesis of the 15-membered macrolactone (-)-amphidinolide P is reported. Key transformations include a Sakurai allylation, a Stille coupling for the formation of a fully functionalized acyclic precursor, and intramolecular transesterification.