Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex.
Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex.
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DOI：
10.1039/c2cc00114d
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发表时间：
2012-03
影响因子：
4.9
通讯作者：
Yaguang Zhao;Huilong Dong;Youyong Li;Xuefeng Fu
中科院分区：
文献类型：
--
作者：
Yaguang Zhao;Huilong Dong;Youyong Li;Xuefeng Fu
采用多用途钴卟啉配合物（TMP-OH）Co.介导有机和水溶性丙烯酸酯和丙烯酰胺的活性自由基聚合（LRP）。这种钴配合物在极性和非极性介质中介导LRP的能力允许直接合成有用的和以前难以制备的功能嵌段共聚物。
Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.