FULGIDES AS SWITCHES FOR INTRAMOLECULAR ENERGY-TRANSFER

FULGIDES AS SWITCHES FOR INTRAMOLECULAR ENERGY-TRANSFER
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DOI:
10.1016/0009-2614(93)85139-f
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发表时间:
1993-10-08
影响因子:
2.8
通讯作者:
EFFENBERGER, F
EFFENBERGER, F
中科院分区:
化学4区
文献类型:
--
作者:
WALZ, J;ULRICH, K;EFFENBERGER, F

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在供体-俘精酰亚胺-受体三元组的分子单元中,从供体到受体的分子内能量转移的可能性取决于光致变色俘精酰亚胺的异构体构型。它示出,开关的这种分子内的能量转移是可能的,通过光致移位的俘精酰亚胺水平之间的陷阱和反陷阱功能。
In a molecular unit which is a donor-fulgimide-acceptor triade, the possibility of an intramolecular energy transfer from donor to acceptor depends upon the isomer configuration of the photochromic fulgimide. It is shown that a switching on and off of this intramolecular energy transfer is possible by photoinduced shifting of the fulgimide levels between a trap and an antitrap function.