First asymmetric total syntheses of fawcettimine-type Lycopodium alkaloids, lycoposerramine-C and phlegmariurine-A.

First asymmetric total syntheses of fawcettimine-type Lycopodium alkaloids, lycoposerramine-C and phlegmariurine-A.
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DOI：
10.1021/ol902437t
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发表时间：
2009-11
期刊：
Organic letters
影响因子：
5.2
通讯作者：
A. Nakayama;N. Kogure;M. Kitajima;H. Takayama
A. Nakayama;N. Kogure;M. Kitajima;H. Takayama
中科院分区：
化学1区
文献类型：
--
作者：
A. Nakayama;N. Kogure;M. Kitajima;H. Takayama

文献摘要

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报道了一种成功的石松色胺-C的不对称全合成方法，包括钴离子介导的Pauson-Khand反应和乙烯基Claisen重排等关键步骤，并将其仿生转化为马尿酸-A。
A successful asymmetric total synthesis of lycoposerramine-C involving such key steps as a cobalt-mediated Pauson-Khand reaction and vinyl Claisen rearrangement and its biomimetic transformation to phlegmariurine-A are described.