Corrosion resistant ZrO2 thin films prepared at room temperature by ion beam induced chemical vapour deposition
Corrosion resistant ZrO2 thin films prepared at room temperature by ion beam induced chemical vapour deposition
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DOI：
10.1016/s0257-8972(01)01615-2
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发表时间：
2002-03-01
影响因子：
5.4
通讯作者：
González-Elipe, AR
中科院分区：
文献类型：
--
作者：
Holgado, JP;Pérez-Sánchez, M;González-Elipe, AR
采用离子束诱导化学气相沉积（IBICVD）方法制备了透明、致密的ZrO_2薄膜。通过透射电子显微镜（TEM）和X射线衍射（XRD）对样品进行了表征。它们作为防腐蚀涂层的性能已经通过循环伏安法对涂有非常薄的氧化锆层（即10、35和100 mn厚）的黄铜样品进行了测试。涂层的防腐蚀效果进行了讨论，与样品的扫描电子显微镜（SEM）和X射线光电子能谱（XPS）的数据进行腐蚀试验。表面形貌和化学成分的变化与从伏安曲线推断的腐蚀程度和机理相关。这些膜呈现非常好的光学性质，并且非常有效地保护黄铜免受腐蚀。这两个事实使IBICVD成为一种非常有前途的方法，用于保存考古或艺术作品，而不影响其视觉外观。(C)2002 Elsevier Science B.V.保留所有权利。
Transparent and very compact ZrO2 thin films have been prepared by ion beam induced chemical vapour deposition (IBICVD). The samples have been characterised by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Their performance as anticorrosion coatings has been tested by cyclic voltametry for samples of brass coated with very thin layers of zirconia (i.e. 10, 35 and 100 mn thick). The corrosion-protective effect of the coatings is discussed in relation with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) data of samples subjected to the corrosion tests. Changes in surface morphology and chemical composition have been correlated with the extent and mechanism of corrosion deduced from the voltametric curves. These films present very good optical properties, and were very effective to protect brass against corrosion. These two facts make IBICVD a very promising method for preserving archaeological or art pieces without affecting their visual appearance. (C) 2002 Elsevier Science B.V. All rights reserved.