In situ observation of electrolytic H 2 evolution adjacent to gold cathodes

In situ observation of electrolytic H 2 evolution adjacent to gold cathodes
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金阴极附近电解 H 2 析出的原位观察

DOI:
10.1039/c3cc46737f
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发表时间:
2014
期刊:
Chem. Commun.
影响因子:
--
通讯作者:
Dillon, S. J.
Dillon, S. J.
中科院分区:
--
文献类型:
--
作者:
Liu, Y.;Dillon, S. J.

文献摘要

被引文献

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在Au电极上电解制氢过程中气体析出的早期阶段,其特征在于在原位透射电子显微镜。结果表明,反应产物分子最初溶解到溶液中,然后在电极附近成核,但不在电极上成核。气体随后润湿电极,并且其连续演化受三相边界线运动支配。
The early stages of gas evolution during electrolytic hydrogen production on Au electrodes are characterized by in situ transmission electron microscopy. The results demonstrate that reaction product molecules initially dissolve into solution and then nucleate near, but not on, the electrodes. The gas subsequently wets the electrodes and its successive evolution is governed by triple phase boundary line motion.