CuCl nanoplatelets from an ionic liquid-crystal precursor
CuCl nanoplatelets from an ionic liquid-crystal precursor
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DOI：
10.1002/anie.200460846
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发表时间：
2004-01-01
影响因子：
16.6
通讯作者：
Taubert, A
中科院分区：
文献类型：
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作者：
Taubert, A
离子液体的研究主要集中在离子液体的合成及其有机化学方面.然而，最近，离子液体也受到了无机材料界的关注。离子液体可以同时作为反应物的溶剂和产物的形貌模板，这使得合成具有新颖或改进性能的无机材料成为可能。原则上，IL可以在合成后回收，从而为无机材料提供生态友好和经济的方法。虽然离子液体是用于合成无机材料的有前途的“一体化”溶剂/模板，但关于该主题的报道很少;它们主要集中在有序金属氧化物[1-5]和金属纳米颗粒上。[6-8]有关离子液体结构组织的最新综述，也可参见参考文献。[9]氯化铜（i）在石化工业中被广泛用作催化剂和纤维素分解的催化剂;[10]因此对改进的CuCl系统有相当大的兴趣。本文介绍了一种新的
Research on ionic liquids (ILs) has focused on the synthesis of and organic chemistry in ILs. Recently, however, ILs have also received attention from the inorganic materials community. Ionic liquids can act as solvents for reactants and morphology templates for the products at the same time, which enables the synthesis of inorganic materials with novel or improved properties. In principle, the IL can be retrieved after synthesis and thus provides an ecologically friendly and economical approach to inorganic materials. While ILs are promising “all-in-one” solvent/templates for the synthesis of inorganic materials, only a few reports on this topic have appeared; they have mainly focused on ordered metal oxides [1–5] and metal nanoparticles.[6–8] For a recent review on the structural organization in ionic liquids, see also ref.[9] Copper (i) chloride is extensively used as a desulfurizing agent in the petrochemical industry and as a catalyst for the denitration of cellulose;[10] there is thus considerable interest in improved CuCl systems. This paper introduces a novel