Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical
Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical
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DOI：
10.1016/j.tetlet.2014.02.005
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发表时间：
2014-03-12
影响因子：
1.8
通讯作者：
Kawabata, Takeo
中科院分区：
文献类型：
--
作者：
Hamada, Shohei;Wada, Yoshiyuki;Kawabata, Takeo
建立了手性氮氧自由基(R，R)-1催化氧化动力学拆分外消旋醇类化合物的方法。该方法对叔丁基芳基甲醇(S=23)的动力学拆分特别有效。(C)2014爱思唯尔有限公司。保留所有权利。
A method for oxidative kinetic resolution of racemic alcohols catalyzed by chiral nitroxyl radical (R,R)-1 has been developed. This method is especially effective for the kinetic resolution of tert-butyl aryl carbinols (s = up to 23). (c) 2014 Elsevier Ltd. All rights reserved.