State-specific reactions of atomic transition-metal ions with molecular hydrogen, hydrogen deuteride, and molecular deuterium: effects of d orbitals on chemistry
State-specific reactions of atomic transition-metal ions with molecular hydrogen, hydrogen deuteride, and molecular deuterium: effects of d orbitals on chemistry
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原子过渡金属离子与分子氢、氘化氢和分子氘的态特异性反应：d 轨道对化学的影响
DOI：
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发表时间：
1987
期刊：
影响因子：
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通讯作者：
P. Armentrout
中科院分区：
文献类型：
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作者：
J. Elkind;P. Armentrout
利用导离子束质谱法研究了整个第一行过渡金属系原子离子与氢分子反应的动能依赖关系。通过改变离子形成的条件，可以得到特定电子态的结果。总结了化学和热力学信息的周期性变化趋势。这些结果可以通过考虑原子离子的自旋和轨道占用来理解。
Guided ion beam mass spectrometry has been used to examine the kinetic energy dependence of reactions of atomic ions of the entire first-row transition-metal series with molecular hydrogen. By varying the conditions under which the ions are formed, results for specific electronic states can be obtained. The periodic trends in the chemistry and derived thermodynamic information are summarized. The results can be understood by considering the spin and orbital occupation of the atomic ions.