CpRu-Catalyzed O-H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds
CpRu-Catalyzed O-H Insertion and Condensation Reactions of α-Diazocarbonyl Compounds
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DOI：
10.1021/ol2000815
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发表时间：
2011-03-18
期刊：
影响因子：
5.2
通讯作者：
Lacour, Jerome
中科院分区：
文献类型：
--
作者：
Austeri, Martina;Rix, Diane;Lacour, Jerome
[CpRu(CH3CN)(3)][PF6]和双胺配体共同催化α-重氮羰基化合物的分解，导致O-H插入和缩合反应。与Rh(II)和Cu(I)络合物相比，CpRu催化剂反应速度快，选择性高。在二恶英的合成中获得了良好的对映选择性。
[CpRu(CH3CN)(3)][PF6] and dilmine ligands catalyze together the decomposition of alpha-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.