Palladium-Catalyzed Three-Component 1:2:1 Coupling of Aryl Iodides, Alkynes, and Alkenes to Produce 1,3,5-Hexatriene Derivatives

Palladium-Catalyzed Three-Component 1:2:1 Coupling of Aryl Iodides, Alkynes, and Alkenes to Produce 1,3,5-Hexatriene Derivatives
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DOI:
10.1002/adsc.200900096
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发表时间:
2009-06-01
影响因子:
5.4
通讯作者:
Miura, Masahiro
Miura, Masahiro
中科院分区:
化学2区
文献类型:
--
作者:
Horiguchi, Hakaru;Hirano, Koji;Miura, Masahiro

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The intermolecular three-component coupling of aryl iodides, diarylacetylenes, and alkenes effectively proceeds in the presence of palladium acetylacetonate and silver acetate as catalyst and base, respectively, to give the corresponding 1:2:1 coupling products, 1,3,5-hexatriene derivatives. A further homologation of the oligoene chain of the three-component coupling products by a simple procedure is also presented.