Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes

Palladium-Catalyzed Dehydrogenative Coupling of Furans with Styrenes
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DOI:
10.1021/ol901570p
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发表时间:
2009-09-17
期刊:
影响因子:
5.2
通讯作者:
Muzart, Jacques
Muzart, Jacques
中科院分区:
化学1区
文献类型:
--
作者:
Aouf, Chahinez;Thiery, Emilie;Muzart, Jacques

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在钯(II)催化和氧化条件下,呋喃与苯乙烯的偶联导致以中等至良好的产率形成Heck型产物。该反应具有高度的区域和立体选择性,主要生成反式烯烃。
Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.