Redox Control for the Recognition of Ag +Ions in a Macrocycle Containing Two SH Groups or an SS Bridge inside the Cavity
Redox Control for the Recognition of Ag +Ions in a Macrocycle Containing Two SH Groups or an SS Bridge inside the Cavity
复制标题
氧化还原控制用于识别包含两个 SH 基团或腔内 SS 桥的大环中的银离子
DOI：
10.1002/anie.199417501
复制
发表时间：
1994
影响因子：
--
通讯作者：
Y. Yano
中科院分区：
文献类型：
--
作者：
T. Nabeshima;H. Furusawa;Y. Yano
一个完全可逆的二硫醇-二硫化物转化调节了大环的识别特性。而开放形式的1A选择性地识别Ag+离子并能将它们运输过膜，封闭形式的1B完全缺乏这种能力。这一概念可能是开发其他具有可变识别特性的受体的基础。
A completely reversible dithiol‐disulfide conversion regulates the recognition properties of the macrocycle 1. Whereas the open form 1A recognizes the Ag+ ion selectively and can transport them across a membrane, the closed form 1B lacks this ability entirely. This concept could be the basis for the development of other receptors with variable recognition properties.