3,3'-Dimethyl-1,1'-ethyl-ene-diimidazolium dibromide.

3,3'-Dimethyl-1,1'-ethyl-ene-diimidazolium dibromide.
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3,3-二甲基-1,1-亚乙基二咪唑鎓二溴化物。

DOI:
10.1107/s1600536809036009
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发表时间:
2009
期刊:
Acta crystallographica. Section E, Structure reports online
影响因子:
--
通讯作者:
Tian,Dan-Bi
Tian,Dan-Bi
中科院分区:
--
文献类型:
--
作者:
Chen,Yu;Song,Wei;Xu,Juan;Cui,Rui-Bo;Tian,Dan-Bi

文献摘要

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标题化合物C10 H16 Br 2N 4是由1-甲基咪唑和1,2-二溴乙烷在甲苯中反应合成的。完整的双阳离子由位于乙烷C-C键中点的晶体学反转中心产生。在晶体结构中,分子间C-H <$Br相互作用较弱,分子沿着B轴成链,分子内C-H <$Br紧密接触也存在。
The title compound, C10H16Br2N4, was synthesized by the reaction of 1-methylimidazole and 1,2-dibromoethane in toluene. The complete dication is generated by a crystallographic inversion centre situated at the mid-point of the ethane C—C bond. In the crystal structure, weak intermolecular C—H⋯Br interactions link the molecules into chains along the b axis and an intramolecular C—H⋯Br close contact is also present.