Pd-Catalyzed Etherification of Nitroarenes
Pd-Catalyzed Etherification of Nitroarenes
复制标题
DOI：
10.1021/acs.organomet.1c00183
复制
发表时间：
2021-07
期刊：
影响因子：
2.8
通讯作者：
Naoki Matsushita;Myuto Kashihara;Michele Formica;Y. Nakao
中科院分区：
文献类型：
--
作者：
Naoki Matsushita;Myuto Kashihara;Michele Formica;Y. Nakao
采用合理设计的新型配体，实现了硝基芳烃与芳醇的pd催化醚化反应。机制的见解被用来设计配体，使氧化加成和还原消除的一个合理的催化循环的步骤是便利的。这里建立的催化体系提供了从硝基芳烃中直接获得一系列不对称二芳醚的途径。
The Pd-catalyzed etherification of nitroarenes with arenols has been achieved using a new rationally designed ligand. Mechanistic insights were used to design the ligand so that both the oxidative addition and reductive elimination steps of a plausible catalytic cycle were facilitated. The catalytic system established here provides direct access to a range of unsymmetrical diaryl ethers from nitroarenes.