Organometallic Complexes of Sumanene
Organometallic Complexes of Sumanene
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Sumanene 有机金属配合物
DOI：
10.1002/9781118742952.ch35
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发表时间：
2013
影响因子：
--
通讯作者：
T. Hirao
中科院分区：
文献类型：
--
作者：
T. Amaya;T. Hirao
金属与弯曲的碳π表面的络合引起了人们的兴趣。在富勒烯碎片(π碗)的情况下，凸面和凹面都可用于配位。在π碗中，我们重点介绍了一种分子碗“Sumanene(C21H12)”，它在苄基位置上有三个亚甲基碳。在这一章中，我们描述了η与RCpM+(Cp=环戊二烯基，M=Fe和Ru)的苄基锂离子配位反应。可以循序渐进地控制锂化。在与CPFe+的络合反应中，首次发现了凹面选择性配位。
Complexation of metals to curved carbon π surfaces has attracted interest. In the case of fullerene fragments (π bowls), both the convex and concave surface are available for coordination. Among π bowls, we focused on a molecular bowl “sumanene (C21H12)” featuring three methylene carbons at the benzylic positions. In this chapter, benzylic lithiation and η6‐coordination with RCpM+(Cp = cyclopentadienyl, M = Fe and Ru) of sumanene are described. The lithiation can be controlled in a step‐by‐step manner. In the complexation with CpFe+, the concave selective coordination is demonstrated for the first time.
影响因子：
15
作者：
Seiders, TJ;Baldridge, KK;Siegel, JS
通讯作者：
Siegel, JS