Supramolecular polymers based on a pillar[5] arene fused cryptand: design, fabrication and degradation accompanied by a fluorescence change
Supramolecular polymers based on a pillar[5] arene fused cryptand: design, fabrication and degradation accompanied by a fluorescence change
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基于柱[5]芳烃稠合穴状配体的超分子聚合物：设计、制造和伴随荧光变化的降解
DOI：
10.1039/c7py01096f
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发表时间：
2017
影响因子：
4.6
通讯作者：
Jiang Juli
中科院分区：
文献类型：
--
作者：
Wang Qi;Cheng Ming;Tian Lu;Fan Quli;Jiang Juli
我们轻松便捷地构建了基于柱[5]芳烃稠合穴状配体的新型线性超分子聚合物，其中三种正交相互作用：四重氢键、基于穴状配体的主客体识别和基于柱[5]芳烃的主客体相互作用结合在一起。此外，通过添加另一种竞争性穴状配体主体，所得线性超分子聚合物可以有效地解聚并伴随荧光变化。
Novel linear supramolecular polymers based on a pillar[5]arene-fused cryptand have been constructed easily and conveniently, in which three orthogonal interactions: quadruple hydrogen bonding, cryptand-based host–guest recognition, and pillar[5]arene-based host–guest interaction were combined together. Furthermore, the resulting linear supramolecular polymers can be effectively depolymerized accompanying a fluorescence change by the addition of another competitive cryptand host.