Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection.
Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection.
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DOI：
10.1021/ja038816y
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发表时间：
2004-01
影响因子：
15
通讯作者：
Y. Matsuo;Ayako Muramatsu;Ryo Hamasaki;Norihiro Mizoshita;Takashi Kato;E. Nakamura
中科院分区：
文献类型：
--
作者：
Y. Matsuo;Ayako Muramatsu;Ryo Hamasaki;Norihiro Mizoshita;Takashi Kato;E. Nakamura
对于一系列具有富勒烯顶端和芳香锥体的分子，在晶体和液晶中观察到柱状堆积的六方或四方堆积，这些分子与Si-C连接。新的羽毛球分子的柱状堆积在结构上是稳定的，但由于富勒烯分子顶部产生了巨大的空穴，所以构象灵活。
Hexagonal or tetragonal packing of columnar stacks in crystals and liquid crystals has been observed for a series of molecules possessing a fullerene apex and an aromatic cone that are connected with a Si-C connection. The columnar stacking of the new shuttlecock molecules is constitutionally stable but conformationally flexible due to the large cavity created on the top of the fullerene molecule.