A polyoxometalate-cyanometalate multilayered coordination network.
A polyoxometalate-cyanometalate multilayered coordination network.
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DOI：
10.1021/ic300263f
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发表时间：
2012-04
影响因子：
4.6
通讯作者：
Jean-Daniel Compain;K. Nakabayashi;S. Ohkoshi
中科院分区：
文献类型：
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作者：
Jean-Daniel Compain;K. Nakabayashi;S. Ohkoshi
在室温常压条件下，由ε-Keggin多氧六环酸盐[PMo（12）O（36）（OH）（4）{La（H（2）O）（4）}（4）]（5+）与Fe（II）（CN）（6）（4-）反应，合成了新型的[ε-PMo（12）O（37）（OH）（3）{La（H（2）O）（5）（Fe（CN）（6）]（0.25）}（4）]网络，其表现出三维多层结构。通过同步辐射X射线晶体学、红外光谱、元素分析和热重分析对该化合物进行了表征。该配位网络构成了与POM单元键合的氰酸酯的第一个实例。
The reaction of the ε-Keggin polyoxometalate (POM) [PMo(12)O(36)(OH)(4){La(H(2)O)(4)}(4)](5+) with Fe(II)(CN)(6)(4-) under typical bench conditions at room temperature and ambient pressure has afforded the novel [ε-PMo(12)O(37)(OH)(3){La(H(2)O)(5)(Fe(CN)(6))(0.25)}(4)] network, which exhibits a three-dimensional multilayered structure. The compound has been fully characterized by synchrotron-radiation X-ray crystallography, IR spectroscopy, elemental analysis, and thermogravimetric analysis. This coordination network constitutes the first example of a cyanometalate bonded to a POM unit.