Biomass to chemicals: Catalytic conversion of glycerol/water mixtures into acrolein, reaction network
Biomass to chemicals: Catalytic conversion of glycerol/water mixtures into acrolein, reaction network
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DOI：
10.1016/j.jcat.2008.04.016
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发表时间：
2008-07-01
影响因子：
7.3
通讯作者：
O'Connor, Paul
中科院分区：
文献类型：
--
作者：
Corma, Avelino;Huber, George W.;O'Connor, Paul
丙烯醛是通过气相甘油/水混合物与沸石催化剂反应获得的。甘油通过一系列涉及脱水、裂解和氢转移的反应进行转化，这些反应由沸石的酸性位点催化。丙烯醛是主要产物；短链烯烃、芳烃、乙醛、羟基丙酮、酸和丙酮也通过一个复杂的反应网络形成。（c）2008爱思唯尔公司。保留所有权利。
Acrolein was obtained by reacting gas-phase glycerol/water mixtures with zeolite catalysts. Glycerol was converted through a series of reactions involving dehydration, cracking, and hydrogen transfer and catalyzed by the acid sites of the zeolite. Acrolein was the major product; short olefins, aromatics, acetaldehyde, hydroxyacetone, acids, and acetone also were formed through a complex reaction network. (c) 2008 Elsevier Inc. All rights reserved.