Inclusion of cyclodextrins in a metallosupramolecular framework via structural transformations
Inclusion of cyclodextrins in a metallosupramolecular framework via structural transformations
复制标题
通过结构转变将环糊精包含在金属超分子框架中
DOI：
10.1039/d1ce01416a
复制
发表时间：
2022
期刊：
影响因子：
3.1
通讯作者：
Konno Takumi
中科院分区：
文献类型：
--
作者：
Somsri Supattra;Kuwamura Naoto;Kojima Tatsuhiro;Yoshinari Nobuto;Rujiwatra Apinpus;Konno Takumi
由D-青霉胺合AuI 3CoIII 2配合物阴离子和水合钠（I）阳离子组成的三维多孔骨架经过溶剂介导的结构转化，生成包含α-环糊精（CD）作为环状三聚体的多层骨架。还报道了通过结构转化将α-CD和γ-CD分子位点选择性地包含到类似的多层框架中。
A 3D porous framework composed of D-penicillaminato AuI3CoIII2 complex anions and aqua sodium(I) cations underwent a solvent-mediated structural transformation to generate a multilayer framework, including α-cyclodextrin (CD) as cyclic trimers. Site-selective inclusion of both α-CD and γ-CD molecules into similar multilayer frameworks via structural transformation is also reported.