A convergent approach to γ-carbonyl vinyl boronates

A convergent approach to γ-carbonyl vinyl boronates
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DOI:
10.1039/b502885j
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发表时间:
2005-01-01
影响因子:
4.9
通讯作者:
Zard, SZ
Zard, SZ
中科院分区:
化学2区
文献类型:
--
作者:
Heinrich, MR;Sharp, LA;Zard, SZ

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γ-羰基乙烯基硼酸酯可以通过S-酰基二硫代碳酸酯(黄原酸酯)与乙烯基硼酸的频哪醇酯的可见光诱导自由基链加成,然后用碱处理来制备。
gamma-Carbonyl vinyl boronates can be prepared by a visible light induced radical chain addition of an S-acyl dithiocarbonate ( xanthate) to the pinacol ester of vinyl boronic acid, followed by treatment with base.