Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
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DOI:
10.1039/b107881j
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发表时间:
2001-01-01
影响因子:
4.9
通讯作者:
Crabtree, RH
中科院分区:
文献类型:
--
作者:
Gründemann, S;Kovacevic, A;Crabtree, RH
2-Pyridylmethylimidazolium salts and IrH5(PPh3)(2) give an [(N-C) IrH2(PPh3)(2)](+) species with the imidazole ring bound in the 'wrong way': at C-5, not at the expected C-2.