Spectroscopy and dynamics of excess electrons in clusters
Spectroscopy and dynamics of excess electrons in clusters
复制标题
团簇中多余电子的光谱学和动力学
DOI：
10.1080/00268970802279555
复制
发表时间：
2007
影响因子：
1.7
通讯作者：
D. Neumark
中科院分区：
文献类型：
--
作者：
D. Neumark
由溶剂分子和多余电子组成的阴离子团簇可以为液体中的电子溶剂化提供新的见解，这是一种本质上的体积现象。本文综述了这类簇的实验和理论研究，主要集中在水簇阴离子，以及碘-水簇，I−(H2O) n和甲醇簇阴离子。特别感兴趣的问题包括这些团簇中的时间分辨动力学与体溶剂化电子的关系，以及这些团簇支持的电子结合基序的性质。
Anionic clusters comprising solvent molecules and excess electrons can provide new insights into electron solvation in liquids, an intrinsically bulk phenomenon. This paper reviews experimental and theoretical studies of this class of clusters, focusing primarily on water cluster anions, , but also on iodide-water clusters, I−(H2O) n , and methanol cluster anions . Issues of particular interest include the relationship of time-resolved dynamics in these clusters to those of bulk solvated electrons, and the nature of the electron binding motifs supported by these clusters.