Volatile Components of the Essential Oils in Galanga (Alpinia officinarum Hance) from Vietnam

Volatile Components of the Essential Oils in Galanga (Alpinia officinarum Hance) from Vietnam
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越南高良姜 (Alpinia officinarum Hance) 精油的挥发性成分

DOI:
10.3136/fstr.7.303
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发表时间:
2001
影响因子:
0.6
通讯作者:
Koji Kato
Koji Kato
中科院分区:
农林科学4区
文献类型:
--
作者:
Tram Ngoc Ly;R. Yamauchi;Koji Kato

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采用水蒸气蒸馏法从高良姜(Alpinia officinarum Hance)的新鲜根茎和干燥根茎中提取挥发油,并通过硅胶柱色谱法将其分离为烃类和含氧化合物组分。通过气相色谱(Kovat指数)和质谱数据确定了28种烃和29种含氧化合物。在新鲜根茎中,含量在1.0%以上的是1,8-桉叶素(50.0%),外-2-羟基-1,8-桉叶素乙酸酯(11.2%),β-卡隆烯(6.4%),α-和β-蒎烯(1.7和2.6%)、β-红没药烯(2.6%)、胡椒酚(2.0%)、柠檬烯(2.0%)、4-萜品醇(1.6%)、胡椒酚乙酸酯(1.2%)和甲基丁香酚(1.0%)。干燥后,根茎中的单萜类化合物(包括烃类和含氧化合物)含量减少,而倍半萜类和芳香族化合物含量增加。干根茎油的主要成分(含量大于2.0%)为β-红没药烯(9.6%),1,8-桉叶素(8.2%),醋酸胡椒酚(5.9%),查维考(5.3%),乙酸丁香油酯(3.7%),α-法尼烯(3.3%)、甲基丁香酚(3.3%)、β-香紫苏烯(2.9%)、α-红没药醇(2.6%)、匙叶烯醇(2.5%)、乙酸法呢酯(2.4%)、乙酸4-羟基肉桂酯(2.3%)。
The essential oils from fresh and dried rhizomes of galanga (Alpinia officinarum Hance) were obtained by hydro-distillation, and fractionated to the hydrocarbon and oxygenated compound fractions by silica gel column chromatography. Twenty-eight hydrocarbons and 29 oxygenated compounds were identified by gas chromatographic (Kovat’s index) and mass spectrometric data. In the fresh rhizome, the main components (over 1.0% in content) were 1,8-cineole (50.0%), exo-2-hydroxy-1,8-cineole acetate (11.2%), β-caryophyllene (6.4%), α- and β-pinenes (1.7 and 2.6 %), β-bisabolene (2.6%), chavicol (2.0%), limonene (2.0%), 4-terpineol (1.6%), chavicol acetate (1.2%), and methyl eugenol (1.0%). On drying the rhizome, the monoterpene fraction (including hydrocarbon and oxygenated compounds) de-creased in content, and the sesquiterpene and aromatic compound fractions increased. Major components of the oil from dried rhizome (over 2.0% in content) were β-bisabolene (9.6%), 1,8-cineole (8.2%), chavicol acetate (5.9%), chavicol (5.3%), eugenyl acetate (3.7%), α-farnesene (3.3%), methyl eugenol (3.3%), β-caryophyllene (2.9%), α-bisabolol (2.6%), spathulenol (2.5%), farnesyl acetate (2.4%), 4-hydroxycinnamyl acetate (2.3%).