Some allylic substituent effects in ring-closing metathesis reactions: allylic alcohol activation.
Some allylic substituent effects in ring-closing metathesis reactions: allylic alcohol activation.
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DOI：
10.1002/chin.199952088
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发表时间：
1999-09
期刊：
影响因子：
5.2
通讯作者：
T. Hoye;Hongyu Zhao
中科院分区：
文献类型：
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作者：
T. Hoye;Hongyu Zhao
[分子式：见正文] 二烯 2a-e 用于研究闭环复分解反应 (RCM) 中的烯丙基取代基效应。发现烯丙基取代基的空间和电子特征都会影响烯烃的反应性。游离烯丙基羟基对 RCM 反应速率具有很大的活化作用。
[formula: see text] Dienes 2a-e were used to study allylic substituent effects in the ring-closing metathesis reaction (RCM). Both the steric and electronic character of the allylic substituents were found to influence alkene reactivities. Free allylic hydroxyl groups exert a large activating effect on the RCM reaction rates.