Generation of Active Ruthenium Catalysts for Hydroarylation of C-C Multiple Bonds from Isolated Ru(IV)=O Species Supported on CeO2
Generation of Active Ruthenium Catalysts for Hydroarylation of C-C Multiple Bonds from Isolated Ru(IV)=O Species Supported on CeO2
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DOI：
10.1246/bcsj.20180144
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发表时间：
2018-09-01
影响因子：
4
通讯作者：
Wada, Kenji
中科院分区：
文献类型：
--
作者：
Miura, Hiroki;Nagao, Masahiro;Wada, Kenji
本文报道了Ru/CeO_2催化剂与邻苯三酚和甲醛在2-甲氧基乙醇中的反应是一种有效的方法，可以生成催化活性的Ru物种用于C-C多重键的氢芳基化反应。各种烯烃都适用于标题反应。固体Ru/CeO2可多次循环使用。
This paper reports that the treatment of Ru/CeO2 with PPh3 and HCHO in 2-methoxyalcohol was an efficient way to generate the catalytically active Ru species for hydroarylation of C-C multiple bonds. A variety of alkenes was applicable toward the title reactions. The solid Ru/CeO2 could be recycled for several times.