The H2O spectrum between 4200 and 5000 cm−1
The H2O spectrum between 4200 and 5000 cm−1
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4200 到 5000 cm−1 之间的 H2O 光谱
DOI：
10.1016/0022-2852(77)90189-8
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发表时间：
1977
影响因子：
1.4
通讯作者：
G. Guelachvili
中科院分区：
文献类型：
--
作者：
J. Flaud;C. Camy‐Peyret;J. Maillard;G. Guelachvili
在60°C的吸收池中加热的水蒸气的光谱被记录在4200到5000 cm−1之间的傅里叶变换光谱仪上。对光谱进行了彻底的分析，得到了改进和扩展的(030)振动态的转动能级集。报道了3ν2带约50条谱线的强度，并对这些强度进行了计算，从而确定了变换偶极矩算符的振动矩阵元。
The spectrum of water vapor heated in an absorption cell at 60°C has been recorded on a Fourier transform spectrometer between 4200 and 5000 cm−1. A thorough analysis of the spectrum has been performed, leading to an improved and extended set of rotational energy levels for the (030) vibrational state. Intensities of about 50 lines of the 3ν2band are reported and a calculation of these intensities has been performed allowing the determination of the vibrational matrix element of the transformed dipole moment operator.