{5,5'-Dimeth-oxy-2,2'-[1,1'-(2,2-dimethyl-propane-1,3-diyldinitrilo)-diethyl-idyne]diphenolato-κO,N,N',O'}copper(II) monohydrate.
{5,5'-Dimeth-oxy-2,2'-[1,1'-(2,2-dimethyl-propane-1,3-diyldinitrilo)-diethyl-idyne]diphenolato-κO,N,N',O'}copper(II) monohydrate.
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DOI：
10.1107/s160053681103889x
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发表时间：
2011-10-01
期刊：
影响因子：
--
通讯作者：
Tiekink ER
中科院分区：
文献类型：
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作者：
Ghaemi A;Rayati S;Elahi E;Ng SW;Tiekink ER
标题络合物水合物[Cu(C23H28N2O4)]·H2O中的四齿双阴离子为CuII原子提供了一个顺式N2O2给体。两个六元CuOC3N螯合环之间形成的二面角为32.14 (8)°，与正方形平面几何构型相比有明显的扭曲。水分子与给定络合物分子中的每个配位氧原子形成氢键。BC面上的超分子层通过C-H⋯O和C-H⋯π相互作用在晶体堆积中形成。
The tetradentate dianion in the title complex hydrate, [Cu(C23H28N2O4)]·H2O, provides the CuII atom with a cis-N2O2 donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC3N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supramolecular layers in the bc plane are formed in the crystal packing through C—H⋯O and C—H⋯π interactions.