Regioselective aromatic C-H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes
Regioselective aromatic C-H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes
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DOI：
10.1039/b511171d
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发表时间：
2005-01-01
影响因子：
4.9
通讯作者：
Miyaura, N
中科院分区：
文献类型：
--
作者：
Ishiyama, T;Sato, K;Miyaura, N
五元杂芳烃与 1,2-二叔丁基-1,1,2,2-四氟乙硅烷的芳香族 C-H 硅烷化反应在 120 ℃、辛烷中、催化量的由 1/2[Ir(OMe)(COD)](2) 和 2-叔丁基-1,10-菲咯啉生成的铱 (I) 配合物的存在下进行。
The aromatic C-H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium( I) complexes generated from 1/2[Ir(OMe)(COD)](2) and 2-tert-butyl-1,10-phenanthroline.