Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates
Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates
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DOI：
10.1021/ol051896l
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发表时间：
2005-10-13
期刊：
影响因子：
5.2
通讯作者：
Du Bois, J
中科院分区：
文献类型：
--
作者：
Wehn, PM;Du Bois, J
Benzene-fused cyclic sulfamates are prepared from ortho-substituted phenolic starting materials through selective C-H amination or olefin aziridination. These unique heterocycles will engage in Ni-catalyzed cross-coupling reactions with aryl- and alkyl-Grignard reagents. Application of modern tools for C-N and C-C bond formation thus makes readily available functional amine derivatives and augments the possible uses for C-H amination in synthesis.
