New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides.
New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides.
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DOI：
10.1039/c1cc10636h
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发表时间：
2011-05
影响因子：
4.9
通讯作者：
Hironori Tsutsumi;Y. Sunada;H. Nagashima
中科院分区：
文献类型：
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作者：
Hironori Tsutsumi;Y. Sunada;H. Nagashima
七核铁羰基簇合物[Fe（3）（CO）（11）（μ-H）]（2）Fe（DMF）（4）（4）对1，2-双（二甲基硅基）苯（BDSB）还原多种酰胺类化合物具有高效催化作用，可减少催化剂用量，缩短反应时间，降低反应温度.
A heptanuclear iron carbonyl cluster, [Fe(3)(CO)(11)(μ-H)](2)Fe(DMF)(4) (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.