The synthesis and X-ray structure of the first cobalt carbonyl-NHC dimer. implications for the use of NHCs in hydroformylation catalysis.
The synthesis and X-ray structure of the first cobalt carbonyl-NHC dimer. implications for the use of NHCs in hydroformylation catalysis.
复制标题
第一个羰基钴-NHC二聚体的合成和X射线结构。
作者：
H. van Rensburg;R. Tooze;Douglas F. Foster;A. Slawin
报道了第一种含氮杂环卡宾配体Co（2）（CO）（6）（IMes）（2）[IMes = 1，3-双（2，4，6-三甲基苯基）咪唑-2-亚基]的羰基钴二聚体的合成、X-射线结构和催化性能。
The synthesis, X-ray structure, and catalytic properties of the first cobalt carbonyl dimer supported by a N-heterocyclic carbene ligand Co(2)(CO)(6)(IMes)(2) [IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] is reported.