SYNTHESIS OF ARYL IODINE(III) DIFLUORIDES BY DIRECT FLUORINATION OF ARYL IODIDES
SYNTHESIS OF ARYL IODINE(III) DIFLUORIDES BY DIRECT FLUORINATION OF ARYL IODIDES
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DOI：
10.1016/s0022-1139(00)82577-4
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发表时间：
1980-01-01
影响因子：
1.9
通讯作者：
RUTHER, G
中科院分区：
文献类型：
--
作者：
NAUMANN, D;RUTHER, G
碘代芳基C6 H5 I、o-XC 6 H4 I（X = F、I）、m-FC 6 H4 I和p-XC 6 H4 I（X = F、Cl、Br、I、CH 3、NO2）与元素氟在−100°C左右的CCl 3F中反应，生成相应的碘代芳基二氟化物，而不会攻击芳环。本文叙述了样品的制备、~（19）F-NMR、~ 1H-NMR和拉曼光谱。
The aryl iodides C6H5I, o-XC6H4I (X = F, I), m-FC6H4I and p-XC6H4I (X = F, Cl, Br, I, CH3, NO2) react with elemental fluorine at about −100°C in CCl3F to form the corresponding aryl iodine difluorides without attack on the aromatic ring. Preparations,19F-nmr,1H-nmr as well as Raman spectra are described.