Olefin Polymerization Catalyst Derived by Activation of a Neutral Monoalkyl Titanium Complex with an Aminopyrrole Ligand Using Triisobutylaluminum and Trityl Borate

Olefin Polymerization Catalyst Derived by Activation of a Neutral Monoalkyl Titanium Complex with an Aminopyrrole Ligand Using Triisobutylaluminum and Trityl Borate
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DOI:
10.1246/cl.2007.1030
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发表时间:
2007-07
期刊:
影响因子:
1.6
通讯作者:
Takahiro Yasumoto;T. Yamagata;K. Mashima
Takahiro Yasumoto;T. Yamagata;K. Mashima
中科院分区:
化学4区
文献类型:
--
作者:
Takahiro Yasumoto;T. Yamagata;K. Mashima

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中性单环钛单苄基配合物3a带有氨基吡咯配体,经Al(iBu)3和[Ph3C][B(C6F5)4]活化后,可成为烯烃聚合的催化剂。
A neutral monocyclopentadienyl titanium monobenzyl complex 3a bearing an aminopyrrole ligand can be activated by treating with Al(iBu)3 and [Ph3C][B(C6F5)4] to became a catalyst for olefin polymeri...