Integrated photoelectrochemical energy storage cells prepared by benchtop ion soft landing.

Integrated photoelectrochemical energy storage cells prepared by benchtop ion soft landing.
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DOI:
10.1039/d2cc02595g
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发表时间:
2022-08-11
影响因子:
4.9
通讯作者:
Laskin, Julia
Laskin, Julia
中科院分区:
化学2区
文献类型:
--
作者:
Prabhakaran, Venkateshkumar;Romo, Joelle;Bhattarai, Ashish;George, Kyle;Norberg, Zachary M.;Kalb, David;Apra, Edoardo;Kottke, Peter A.;Fedorov, Andrei G.;El-Khoury, Patrick Z.;Johnson, Grant E.;Laskin, Julia

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聚氧乙烯酸盐阴离子PW12O403−的特殊光致变色和氧化还原特性已被开发用于太阳能转换和存储的集成光电化学储能电池。使用台式离子软着陆消除强配位阳离子导致装置的最大功率输出增加了1.370%。此外,光电阴极显示出明显的颜色变化,从明确的蓝色照射后,这保证了先进的智能窗和光致变色透镜的IPES电池的潜在应用。软着陆消除了Keggin聚氧乙烯酸盐光电阴极中的抗衡阳离子,从而使同时收集和存储太阳能的新型器件的最大功率输出增加了370%。
The exceptional photochromic and redox properties of polyoxometalate anions, PW12O403−, have been exploited to develop an integrated photoelectrochemical energy storage cell for conversion and storage of solar energy. Elimination of strongly coordinating cations using benchtop ion soft landing leads to a ∼370% increase in the maximum power output of the device. Additionally, the photocathode displayed a pronounced color change from clear to blue upon irradiation, which warrants the potential application of the IPES cell in advanced smart windows and photochromic lenses. Soft landing eliminates counter cations from Keggin polyoxometalate-based photocathodes, resulting in a ∼370% increase in maximum power output from a novel device that simultaneously harvests and stores solar energy.
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