Spirobis(pentagerma[1.1.1]propellane): A Stable Tetraradicaloid
Spirobis(pentagerma[1.1.1]propellane): A Stable Tetraradicaloid
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DOI：
10.1021/ja401650q
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发表时间：
2013-05-08
影响因子：
15
通讯作者：
Sekiguchi, Akira
中科院分区：
文献类型：
--
作者：
Ito, Yuki;Lee, Vladimir Ya.;Sekiguchi, Akira
在这方面的贡献，我们报告了spirobis（pentagerma[1.1.1]propellane）衍生物作为一种新型的分子结构在除尘器化学，具有两个螺稠合[1.1.1]propellane单位，并代表一个稳定的tetraradicaloid物种。锗桥头之间的相互作用的性质的关键问题进行了探讨计算，揭示了弱成键之间的相互作用的形式不成对的电子。
In this contribution, we report a spirobis(pentagerma[1.1.1]propellane) derivative as a novel type of molecular architecture in duster chemistry that features two spiro-fused [1.1.1]propellane units and represents a stable tetraradicaloid species. The crucial issue of the nature of the interaction between the germanium bridgeheads was probed computationally, revealing weak bonding interactions between the formally unpaired electrons.